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Some Silicone Questions

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Hey everyone! I just made a silicone mold and was out on the porch for a good hour collecting the pooled up silicone at the bottom and pouring it back onto the head. I thought it was cured enough so I left it and went inside. I just went to check and it looks like quite a bit pooled at the bottom. The mold looks a little thin, but it hasn't fully cured yet.

Can you add more silicone to a mold AFTER it's completely cured? I'm assuming the new silicone will just fuse to the mold, but I wanted to double check before I put in another silicone order.

This is my second time making a silicone mold. How thick does the mold have to be to be useable?

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